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Monday 30 June 2014
Lesson Plan Buffer Solution
LESSON PLAN BUFFER SOLUTION
Unit Education : Senior High School
Subjects : Chemistry
Class / Semester : XI IPA / 2
Material : Buffer Solution
Time : 4 meetings (4 x 3hours)
Unit Education : Senior High School
Subjects : Chemistry
Class / Semester : XI IPA / 2
Material : Buffer Solution
Time : 4 meetings (4 x 3hours)
I.
Core
Competencies :
Cc 1 :
Internalize and apply the relligious tennates attended
Cc2 :
Internalize and apply honest behaviour, discipline, responsible, caring (mutual
assistance, collaborative, tolerant, peacefull) good manners, responsive and
proactive and show an attitude as part of solution of problems in effective
interaction by social and natural environment and place him/her self as such to
reflect the nationality among other nations acrros the world
Cc 3 :
Understand apply and analyze factual, conceptual, procedural and metacognitive
knowledge grounded on curiousity feeling about knowledge, technology, art,
culture, and humaniora by humanity, nationality, citizenship, and civilizatiton
related to phenomena and events and
apply procedural knowledge on specific are of study appropiate with talent and
his/her interset for problem solving.
Cc
4 : Manage, reason and present in
concreate and abstract domain related with what to develop in his/her study in
the school by self and capable of using the scientific method.
II. Achievement Indicators Basic
Competence and Core Competence
KD of KI 1:
1.1 Recognizing the regularity of the structure of matter
as the particle greatness of Almighty God and
the knowledge of the structure of matter particles as a
result of human creative thinking that truth is tentative.
Indicators :
·
Exalts the greatness of God Almighty
·
Recognizing that
the conditions set by the Almighty God is
the best for us.
KD of KI 2:
2.1 Demonstrate scientific behavior (curious,
disciplined, honest, objective, open, able to distinguish fact and opinion, tenacious, thorough, responsible, critical,
creative, innovative, democratic, communicative) in
design and conduct experiments
and discuss the embodied
in everyday behaviors.
Indicators:
·
Curiosity
·
Honestly in
using experimental data to prove a legal chemical
basis (using the data for what it is and the results
are in accordance with the data experiments)
·
Thorough in processing and
analyzing the data (perform legal proof basic chemical and consistent
trace the steps and truth results)
·
Tenacious in finding the source
of knowledge that supports the completion of problem
(can resolve the problem at
the beginning to the end of
the trace the correct steps).
KD of KI 3:
3.13 Analyzing the nature of the role of the buffer solution in the living
body
Indicators:
·
Mention sense buffer solution
·
Identifying the properties of buffer
solution through trial
·
Explain formation solution buffer
·
Explain relationship nature of
the buffer on blood
KD of KI 4:
4.8 Design, conduct, and conclude
and present the results of experiments to determine the nature of the buffer
solution
Indicators:
·
Designing experiments to investigate the
nature of the buffer solution
·
Experimenting nature solution buffer on
some solution
·
Observe and record the experimental
data solution buffer
·
Process and m enganalisis
experimental data solution buffer
·
Summing properties by the addition of
buffer solution slightly acids, bases or dilution
·
Communicate the nature of the experimental
results buffer solution
III.
Learning Objectives
1.
Students may be aware of the regularity of the
solution as a manifestation of the greatness of God Almighty.
2.
Students can demonstrate positive attitudes
(individual and social) in group discussions
3.
Students can demonstrate the behavior and attitude of
accepting, appreciating, and executing honesty, rigor, discipline and
responsibility
4.
Students may mention the sense of a buffer solution
5.
Students can identify the properties of buffer
solution through trial
6.
Students can explain the formation of solution buffer
7.
Students are able to explain relationship nature of
the buffer on blood
8.
Students can design an experiment to investigate the
nature of the buffer solution
9.
Students can discriminate n trials of an nature
solution on some solution.
10. Students can
observe and record the experimental data solution buffer on some solution.
11. Students can
either though and analyzing experimental data buffer solution.
12. Students can
infer properties of the solution by the addition of slightly acids, bases or
dilution.
13. Student can
determine the pH of the solution buffer.
14. Student can
determine graph relationship change pH on titration acid alkali for explain
nature solution buffer.
15. Student can
presented result trial use system correct language.
IV. Learning
Materials
Ø
Components of a buffer solution
Buffer solution can be prepared by mixing a weak acid with its conjugate base or a weak base with its conjugate acid. Example:
a. acid buffer solution, CH3COOH (aq) + CH3COONa (aq)
Data acidic pH buffer solution is determined by calculation based on the equilibrium reaction:
HA H + + A-
Ka = [H +] [A-]
[HA]
[H +] = Ka. [HA]
[A-]
Note: [HA] = concentration of acid
[A-] = concentration of salt
b. alkaline buffer solution, NH3 (aq) + NH4Cl (aq)
Data alkaline pH buffer solution were determined by calculation based on the equilibrium reaction:
MOH M + + OH-
Ka = [M +] [OH-]
[MOH]
[OH-] = Ka. [MOH]
[M +]
Note: [MOH = concentration of base
[M +] = concentration of salt
Buffer solution can be prepared by mixing a weak acid with its conjugate base or a weak base with its conjugate acid. Example:
a. acid buffer solution, CH3COOH (aq) + CH3COONa (aq)
Data acidic pH buffer solution is determined by calculation based on the equilibrium reaction:
HA H + + A-
Ka = [H +] [A-]
[HA]
[H +] = Ka. [HA]
[A-]
Note: [HA] = concentration of acid
[A-] = concentration of salt
b. alkaline buffer solution, NH3 (aq) + NH4Cl (aq)
Data alkaline pH buffer solution were determined by calculation based on the equilibrium reaction:
MOH M + + OH-
Ka = [M +] [OH-]
[MOH]
[OH-] = Ka. [MOH]
[M +]
Note: [MOH = concentration of base
[M +] = concentration of salt
Ø How
a buffer solution
If the acid is added, the H + ions and the acid will react with ions to form CH3COOH CH3COO-pH so prices are likely to remain.
If a base is added, the OH-ions will be neutralized by CH3COOH, pH so prices are likely to remain
If the acid is added, the H + ions and the acid will react with ions to form CH3COOH CH3COO-pH so prices are likely to remain.
If a base is added, the OH-ions will be neutralized by CH3COOH, pH so prices are likely to remain
Ø The
nature of the buffer solution
The nature of the buffer solution is to maintain the pH value if :
To a solution buffer was added a bit of acid or base.
The solution was diluted
The nature of the buffer solution is to maintain the pH value if :
To a solution buffer was added a bit of acid or base.
The solution was diluted
V. Learning Method
The method
used is scientific approach SETS
Guided
Inquiry Learning Model
VI. Learning
Resources
·
Michael
Proto, Chemistry Class X SMA / MA, grants, Jakarta
·
Handbook of
Chemistry vol 1, Allied Chemical Activity Book Student, and hands out
·
Worksheets
·
Newspaper
·
Video
·
Module
VII. Learning Media (Media,
Equipment, Materials)
·
Newspaper
·
Chemistry Books
·
Module
·
Video
VIII. Learning Steps Activity
v Meeting 1
Time
|
Activity
|
|
Introduction
15 minutes
|
|
|
Core
activities
90 minutes
|
1.
Student asked m engkaji literature on buffer
solution.
2.
Teachers m engajukan question whether all solutions
can maintain its pH? Why a solution can maintain its pH? What are the
benefits of a buffer solution in body creature life?
3.
The teacher gives material early about understanding
solution buffer and its properties
4.
Teachers provide data results experiment about
solution buffer and memberika n example way determine the pH of the solution
buffer.
5.
Student requested for determine the pH of the data
results experiments.
|
|
Closing
30minutes
|
·
Teachers with students to make
inferences about solution nature
solution buffer and
way determination
pH.
· The teacher asks student search
literature about role buffer in life day-to-day
|
v Meeting 2
Time
|
Activity
|
|
Introduction
15 minutes
|
· Students respond regards and
questions relating to the conditions of teachers and attendance
· The teacher asks task read
literature about application nature solution blood in life daily
· The teacher divides teachers into
group large
|
|
Core
activities
90 minutes
|
· Students discuss result task read
· The teacher asks student present
result discussion
|
|
Closing
30 minutes
|
·
Teachers with students to make inferences about the
discussion.
·
The teacher asks student learn experiment solution
buffer for activity laboratory
|
v Meeting 3
Time
|
Activity
|
|
Introduction
15 minutes
|
( Phase I : Orientation of students to
the problem )
a. Teachers deliver the learning objectives ( KD and
indicators )
b . Teachers give a pretest to determine students'
prior knowledge of the material to be covered
c . Teachers motivate students by way of delivering
usability buffer material in everyday life and do apperception .
d . Teachers pose problems in daily life related to
the buffer material.
|
|
Core activities
90 minutes
|
( Phase II : Organizing students to learn )
a. The teacher organizes
students into each group .
b . The teacher instructed
the students to open a worksheet that has distributed 01 .
c . The teacher gives
instructions to students on how to work on the problems posed in the LKS 01 .
( Phase III : Guiding investigation of
individual and group )
a. Teachers help students
define and organize tasks to be performed as set out in its LKS respectively
( LKS/XI-2/LP/01 ) in groups
b . The teacher directs
students to conduct research in the theory of the issues expressed in the
article O - FISH in LKS 01 by utilizing the students as well as other
reference books that are relevant to the task at hand
c . Teachers guide
students to create a temporary answer ( hypothesis ) of the issues expressed
in the article O - FISH in LKS 01 .
( Phase IV : Developing and presenting the works )
a. Teachers provide
guidance in order to do brainstorming in groups to answer all pertanyanyaan
in LKS 01 .
b . Teachers check the
work of each group before it was read in class .
( Phase V : Analyze and evaluate the problem-solving
process )
a . Directing each group
to check back LKS group's work
b . One group was
appointed to read the group's work in LKS and other groups provide questions
/ comments / input .
c . The teacher gives the
answer reinforcement developed in the discussion .
|
|
Closing
15 minutes
|
The final
activity ( + 5 min )
a. Teachers provide an appreciation of the report of
the discussion that has been collected by each group
b . Teachers submit action plan at the next meeting
.
|
v Meeting 4
Time
|
Activity
|
|
Introduction
15 minutes
|
· Students respond regards and
questions relating to the conditions of teachers and attendance.
· Teachers charge task report as
result psychomotor and cognitive.
|
|
Core
activities
90 minutes
|
· The teacher told student for
presented result report according to dated.
· Other students scrutinize and
prepare question for student presentations.
· Teachers see course process
presentation and answer question
|
|
Closing
30 minutes
|
· Teachers with students to make
inferences about activity presentation.
· The teacher asks student work
questions exercise in LKS.
|
IX. Assessment
Attitudes and Skills Assessment process experimental data include:
1. Spiritual Attitude
a.
Technique : Observations
b.
Help
Instruments :
Observation Sheet
c.
Grating :
Attitude / Value
|
Item Instrument
|
|
1
|
Realizing that all the gifts of God Almighty
|
Be grateful
|
2
|
Realizing that God Almighty will provide convenience
|
Pray prev and after doing something
|
2.
Social
Attitudes
a.
Technique : Observations
b.
Help
Instruments :
Observation Sheet
c.
Grating :
Attitude / Value
|
Item Instrument
|
|
1
|
Honesty
|
·
Not
cheating during a test.
·
Not
plagiarism.
·
Do not
steal from friends.
|
2
|
Discipline
|
·
Arrive on
time
·
Tasks on
time
·
Orderly,
obedient
·
Dressed
and well groomed
|
3
|
Responsibility
|
·
Return
the borrowed items
·
Doing a
good job
·
Accept
the risk of acts committed
|
3. Knowledge
a.
Technique : Observations
b.
Help
Instruments :
Observation Sheet
c.
Grating :
Attitude / Value
|
Item Instrument
|
|
1
|
Curiosity
|
·
Able to
answer questions
·
Being
able to predict the solubility of the precipitate in
·
Being
able to calculate the solubility and solubility results
·
Able to
understand the concepts of solubility and solubility product
|
4.
Skill
a. Technique :
Observation
b. Help Instruments :
Observation Sheet
c. Grating :
Attitude / Value
|
Item Instrument
|
|
Patient
|
Preparing den tool materials with good
Not in a hurry at the time of trial
|
|
Not interfere friend
|
Willingness perform duties in conformity deal
|
|
Discipline
|
Orderly in conducting experiments in laboratory
|
|
Responsibility
|
Replace if damaged the appliance
|
|
Thorough
|
Be careful when experimenting
|
|
Net
|
Always clean the instrument after use
|
|
Neat
|
Using a lab coat properly
|
|
Honest
|
Reported experimental data it is
|
X. Valuation
Worksheet 01: BUFFER SOLUTION
LKS buffer (BUFFER)
Ø Objectives:
Studying the
nature of the buffer solution and not the addition of a little acid buffer,
bases, or dilution.
Ø Theory:
Most of the metabolic processes in
living organisms takes place at pH constant. Enzymes work well in certain pH.
Bacteria multiply at pH particular. Blood pH is relatively constant at 7.4. To
maintain the pH of the solution to prevent changes are striking, use substances
that are buffers. Buffer solution is a solution that containing a weak acid
with its salt, or a weak base with its salt.
Ø Tools and
Materials:
o Test tubes
(4) and the rack
o M NaCl
solution
o CH3 solution
o COONa 0.1 M
o Pipette 4
o HCl solution
o solution of
NH3 0.1 M
o 10 ml
measuring cup (1)
o M NaOH
solution
o solution of
NH4
o Cl 0.1 M
o Universal
indicator
o solution of
CH3
o COOH 0.1 M
o distilled
water
o 100 ml
beaker (1)
Ø Procedure.
1.
Insert the 5 ml of H2O into the reaction tube. Give 1
sheet indicators universal. Record the pH prices. Divide the solution into 2
and enter into test tube.
2.
Into the first test tube, Adding 2 drops of 0.1 M NaOH
Record the pH prices.
3.
Into the second test tube, add 2 drops of HCl 0.1 M.
Record the pH prices.
4.
Put to the test tube 2 ml CH3 COOH + 2 ml of 0.1 M CH3
COONa 0.1 M
5.
Calculate the pH, then the solution is divided into 2
pieces of test tubes
6.
Into the first test tube, add 2 drops of 0.1 M NaOH,
calculate the pH of its
7.
Into the second test tube, add 2 drops of 0.1 M HCl,
calculate the pH of its
8.
Put to the test tube 2 ml of NH4 OH + 2 ml of 0.1 M
NH4 Cl 0.1 M
9.
Calculate the pH, then the solution is divided into 2
pieces of test tubes
10. Into the
first test tube, add 2 drops of 0.1 M NaOH, calculate the pH of its
11. Into the
second test tube, add 2 drops of 0.1 M HCl, calculate the pH of its
Observation
pH
|
H2O
|
+ NaOH
|
+ HCl
|
First
|
.....
|
____
|
____
|
mix
|
___
|
.....
|
.....
|
a.
b.
pH
|
CH3COOH + CH3COONa
|
+ NaOH
|
+ HCl
|
First
|
.....
|
____
|
____
|
mix
|
___
|
.....
|
.....
|
c.
pH
|
NH4OH + NH4Cl
|
+ NaOH
|
+ HCl
|
First
|
.....
|
____
|
____
|
mix
|
___
|
.....
|
.....
|
Question.
1. Solution
of NH4OH + NH4Cl called buffer solution .......
2. Solution
of CH3COOH + CH3COONa buffer solution called .......
3. Give the
conclusion of the experiment above.
A. Answer the question below correctly!
1. What is a
buffer solution?
2. Provide
an example of a buffer solution in everyday life!
3. Stand is
divided into 2. Explain!
4. Describe the properties of a
buffer solution?
B. Choose one best answer!
5. Among the
mix below includes buffer solution, except ....
a. NH4OH and
NH4Cl
b. HCN and
KCN
c. CH3COOH and CH3COONa
d. H2CO3 and
KHCO3
e. Ca(OH)2
and CaCl2
6. The
function of the buffer solution in the blood system is to maintain .....
a. Blood
acidity
b.
fibrionogen blood ..
c. Blood Hb
d. White
blood cells from blood
e. Red blood
cells from blood
7. Some
solution reacted as follows.
(1) 100 ml
of 0.1 M acetic acid and 100 ml of 0.1 M NaOH
(2) 100 ml
of 0.2 M acetic acid and 100 ml of 0.1 M NaOH
(3) 100 ml
of 0.1 M hydrochloric acid and 100 ml of NH 4 OH 0.1 M
(4) 100 ml
of 0.05 M hydrochloric acid and 100 ml of NH 4 OH 0.1 M
Mixture on
top of which forms a buffer solution is
a. (1), (2),
and (3)
d. (4)
b. (1) and
(3)
e. all
solution
c. (2) and
(4)
scores obtained
Value =
--------------------------- x 100
maximum score
|
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